Tuesday, August 13, 2019

Quantum mechanics can fail at will

Quantum mechanics can fail at will (Summary)


Observe matter [diffraction × inteference], re Arndt and C_60, falsify Hund's paradox.  Quantum mechanics macroscopically fails given optically resolved 2-trifluoromethyl-D_3-trishomocubane as a 2 kelvin vacuum supersonic-expanded molecular beam. 

The Arrhenius equation-calculated Hund's paradox racemization constant is 10^(-36,900)/sec at most. The observable universe - quarks, electrons, neutrinos, photons - is estimated 10^97 particles.   Quantum mechanics fails to predict the observed outcome - no racemization.

“Like every particle in any matter-wave interferometer, each molecule only interferes with itself.”  There is no wavefunction dissipation or decoherence within the grating's near field.  If it happens in practice, that it is impossible in principle is irrelevant.

https://www.quantumnano.at/research/matter-wave-technologies/far-field-diffraction/the-origin-c60-diffraction/


Sodium metalization of 1,4-dimethoxybenzene. then menthyl chlorocarbonate from menthol into phosgene plus pyridine in ether.  Order of addition matters.

Derivatized  Cookson's diketone is best [2π + 2π] obtained by continuous flow thin film 365 nm LED photolysis, 2+ kg/day, 



Balance of synthesis is re Sharapa, Scheme 2, DOI:10.1002/ejoc.201001731, updated.


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